How to Achieve 90%+ TiO₂ Recovery from Complex Titanium Ores?

2026-01-15

Achieving 90%+ titanium dioxide (TiO₂) recovery from complex titanium ores requires a thorough understanding of the ore’s mineral composition, processing technologies, and optimization techniques. Titanium is typically found in ores like ilmenite (FeTiO₃), rutile (TiO₂), and leucoxene, but its recovery becomes challenging when dealing with complex mineral assemblages. Here’s a systematic approach to achieving high TiO₂ recovery:

1. Comprehensive Ore Characterization

• Study the mineralogical and chemical composition of the ore to identify the titanium-bearing minerals (ilmenite, rutile, anatase, etc.) and impurities (iron, silica, magnesium, aluminum, etc.).
• Use techniques like X-ray diffraction (XRD), scanning electron microscopy (SEM), and mineral liberation analysis (MLA) to assess grain size, liberation, and association of minerals.

2. Beneficiation (Pre-concentration)

Physical Beneficiation:

• गुरुत्वाकर्षण अलगाव: Use spiral concentrators or shaking tables to exploit the difference in the specific gravity of TiO₂ minerals and gangue materials.
• मैग्नेटिक सेपरेशन: Remove magnetic impurities (e.g., magnetite, hematite) and concentrate slightly magnetic ilmenite minerals.

• इलेक्ट्रोस्टैटिक पृथक्करण: Separate conductive TiO₂ minerals (ilmenite, rutile) from non-conducting gangue.

  फ्रोथ फ्लोटेशन:

• Use flotation techniques with selective collectors to remove gangue (e.g., silicates, carbonates) and enhance TiO₂ recovery.

  Proper beneficiation can significantly increase the grade of the ore before further processing.

3. Hydrometallurgical Techniques

For complex ores, chemical processing is often required:

• लीचिंग:
  • Treat the ore with leachants like sulfuric acid, hydrochloric acid, or alkali to dissolve undesired impurities (e.g., iron).
  • In the case of ilmenite, enhance the dissolution of FeO/Fe₂O₃ while retaining titanium in the residue.

• Advanced techniques like pressure leaching or reductive acid leaching improve TiO₂ enrichment.

  Example: Sulfate or hydrochloric acid process can target iron removal while concentrating TiO₂.

4. Pyrometallurgical Upgrading

• धातुगलन Convert ilmenite to synthetic rutile (>90% TiO₂) through processes like:
  • Becher Process: Reduce ilmenite with coal to convert FeO to metallic iron, which can be subsequently separated, leaving TiO₂-enriched residue.
  • क्लोरीनीकरण React ilmenite or titanium slag with chlorine at high temperatures to produce titanium tetrachloride (TiCl₄), which can be purified by distillation and then oxidized to produce pure TiO₂.

5. Combination of Techniques

Many processes require a combination of the above steps to optimize TiO₂ recovery. For example:

• Beneficiation followed by smelting and acid leaching can eliminate impurities effectively while concentrating TiO₂.
• Advanced flowsheet designs integrate flotation, gravity separation, and chemical upgrading for best results.

6. Optimization of Key Parameters

• पीएच नियंत्रण: Optimize pH during flotation or leaching to ensure maximum TiO₂ recovery while minimizing impurity removal.
• Temperature and Reductant Levels: In pyrometallurgical processes, control temperature and reducing agent levels for effective iron separation.
• कण आकार: Ensure proper comminution for maximum liberation of titanium minerals.

7. Tailings Management and Recycling

• Recycle intermediates and tailings to recover any remaining TiO₂.
• Reprocess fine particles often lost in separation processes to prevent TiO₂ losses.

8. उन्नत प्रौद्योगिकियाँ

• Consider innovative approaches like plasma smelting, bioleaching, or advanced solvent extraction to address complex ores more efficiently.

9. Case-Specific Process Design

• Each ore deposit is unique. Pilot-scale testing and custom flowsheet design ensure optimal recovery for a specific deposit.

By combining effective beneficiation, appropriate chemical or thermal treatment, and meticulous optimization, you can achieve consistent TiO₂ recoveries greater than 90%, even from challenging ores. Close attention to the mineralogy and careful adjustment of process parameters is critical in overcoming the difficulties posed by complex titanium ores.

प्रोमिनर (शंघाई) माइनिंग टेक्नोलॉजी कं., लिमिटेड, वैश्विक स्तर पर पूर्ण खनिज प्रसंस्करण और उन्नत सामग्री समाधान प्रदान करने में विशेषज्ञता रखती है। हमारा मुख्य ध्यान निम्नलिखित पर केंद्रित है: सोने की प्रक्रिया, लिथियम अयस्क का लाभ उठाना, औद्योगिक खनिज। एनोड सामग्री उत्पादन और ग्रेफाइट प्रसंस्करण में विशेषज्ञता।

उत्पादों में शामिल हैं: पीसने और वर्गीकरण, पृथक्करण और पानी निकालना, सोने का शोधन, कार्बन/ग्रेफाइट प्रसंस्करण और लीचिंग सिस्टम।

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