How is wolframite beneficiated for tungsten extraction?
Wolframite ((Fe,Mn)WO₄) is one of the primary ores used for tungsten extraction. Beneficiation is the process of concentrating the ore and removing impurities to make it suitable for tungsten production. The beneficiation of wolframite involves several steps designed to separate it from other minerals and impurities based on its physical and chemical properties:
1. Ore Crushing and Grinding
- The raw ore is crushed and ground to liberate wolframite particles from the surrounding gangue (host rock). This is a critical step to ensure efficient separation later.
2. 重力分选
- Wolframite has a high specific gravity compared to most gangue minerals, making gravity separation the primary method of concentration.
- Equipment used for gravity separation includes:
- 摇床: Separate wolframite based on differences in density.
- 摇床: Used to further concentrate the ore by stratifying particles of different densities.
- 螺旋分离器: Enhance separation based on density differences.
- This step removes lighter minerals and concentrates wolframite.
3. 磁选法
- Wolframite is weakly magnetic and can be separated from non-magnetic impurities using magnetic separation techniques.
- High-intensity magnetic separators are often used to separate wolframite from minerals like cassiterite or silicates.
4. Flotation (Optional Step)
- If impurities such as sulfides (e.g., pyrite or arsenopyrite) are present, flotation may be used as a supplementary separation method. Wolframite can be selectively floated or recovered while rejecting sulfide impurities.
- Specific reagents (collectors, depressants, frothers, etc.) may be added to aid the process.
5. Hydrometallurgical Purification
- After concentrating wolframite via physical methods, chemical processes can be used to further purify the concentrate. This may involve leaching or scrubbing steps to remove residual impurities like phosphorus, sulfur, or arsenic.
6. Roasting and Chemical Processing (Tungsten Extraction)
- Once a high-quality wolframite concentrate is obtained, it is processed chemically:
- Wolframite is often roasted to remove unwanted impurities.
- The roasted concentrate is then treated with sodium hydroxide or sodium carbonate to dissolve tungsten and yield sodium tungstate.
- From the sodium tungstate solution, tungsten is precipitated as tungsten acid or ammonium paratungstate (APT), which are intermediate products in tungsten production.
Factors Affecting Beneficiation:
- 矿物成分: The presence of other tungsten minerals like scheelite or impurities like sulfides affects the choice of beneficiation techniques.
- 粒径
: The ore must be finely ground to liberate wolframite from gangue, but excessive grinding can lead to loss of tungsten in slimes.
- 经济考虑: Optimum beneficiation techniques are chosen based on cost, scalability, and efficiency.
结论：
Wolframite beneficiation relies heavily on physical separation methods such as gravity and magnetic separation, supported by flotation and selective chemical processing when necessary. These methodologies help produce a concentrated wolframite product that is further processed chemically to extract tungsten.
普明矿业（上海）科技有限公司专注于为全球提供完整的矿物加工和先进材料解决方案。我们的核心重点包括：金矿加工、锂矿选矿、工业矿产。专业从事阳极材料生产和石墨加工。
产品包括：研磨与分级、分离与脱水、金精炼、碳/石墨加工和浸出系统。
我们提供端到端服务，包括工程设计、设备制造、安装和运营支持，并提供 24/7 的专家咨询。
我们的网站网址：https://www.prominetech.com/
我们的电子邮件：[email protected]
我们的销售：+8613918045927（Richard），+8617887940518（Jessica），+8613402000314（Bruno）
