How is scheelite mineral beneficiated for maximum tungsten recovery?

2025-09-18

Beneficiating scheelite ( (\text{CaWO}_4) ), a primary tungsten mineral, involves a series of processes aimed at maximizing tungsten recovery while minimizing impurities. The process generally involves a combination of physical and chemical methods, customized based on the ore’s composition, mineralogical characteristics, and economic considerations.

Here’s an overview of the scheelite beneficiation process for maximum tungsten recovery:

1. Ore Preparation: Crushing and Grinding

• Назначение: Reduce the ore to a fine particle size to liberate scheelite from the gangue minerals.
• Этапы:
  • Crushing the ore to a manageable size.
  • Grinding the ore to achieve the required liberation size, typically around 0.2–0.5 mm (but depends on the mineral’s particle size).
  • Care is taken to avoid overgrinding, which can adversely affect the downstream processes.

2. Гравитационное обогащение

• Назначение: Exploit the high specific gravity of scheelite (~6.1) compared to the gangue minerals.
• Методы:
  • Встряхивающие столыиspiral concentrators are commonly used to separate scheelite particles.
  • Pre-concentration may be employed to discard a portion of unwanted gangue early in the process.

Gravity separation is effective for coarser particles, but its efficiency decreases for very fine fractions.

3. Froth Flotation

• Назначение: Further concentrate scheelite by separating it from silicate and sulfide impurities.

• Mechanism:

  • Scheelite is a calcium tungstate mineral and exhibits hydrophilic properties in its natural state, requiring surface modification for flotation.
  • Chemicals Used:
  • Коллекторы: Fatty acids (e.g., oleic acid) are commonly used as collectors to make scheelite hydrophobic.
  • Депрессанты: Soluble silicates (e.g., sodium silicate) and water glass suppress silicate and carbonate minerals.
  • Модификаторы pH: Adjusting to an optimal pH (usually 8–11) enhances separation efficiency.

  Various flotation reagents may be customized based on the ore’s composition.

4. Magnetic Separation (if needed)

• Назначение: Remove paramagnetic and ferromagnetic impurities (e.g., garnet or ilmenite) from the scheelite concentrate.
• Оборудование: High-intensity magnetic separators are often employed.

Scheelite itself is non-magnetic, but this step is useful when the ore contains magnetic contaminants.

5. Leaching and/or Roasting (Optional for High Purity)

• Назначение: Improve tungsten recovery and purity.
  • Ores with impurities like molybdenum sulfides may require intermediate steps, such as roasting or chemical leaching.
• Process Options:
  • Roasting to oxidize sulfide minerals.
  • Acid leaching to remove specific impurities.

6. Final Concentrate Filtration and Drying

• After the enrichment steps, the scheelite concentrate is filtered to remove excess water and dried to prepare it for downstream processing, such as tungsten extraction.

Key Considerations for Maximum Recovery

1. Ore Mineralogy: A detailed study of the ore (e.g., liberation size, mineral associations) helps optimize the beneficiation process.
2. Grade-Recovery Balance: Achieving maximum recovery without compromising the concentrate grade is essential for economic feasibility.
3. Соответствие экологии: Minimize the environmental impact, especially with flotation and chemical usage.
4. Process Customization: Modifications to the process are often required for ore-specific challenges, such as high impurity levels or complex mineral compositions.

Результат

• The final scheelite concentrate typically contains 60–70% tungsten trioxide ( (\text{WO}_3) ), suitable for smelting and further tungsten processing.
• Recovery rates vary, but well-optimized processes can achieve up to 80–90% tungsten recovery from the ore.

By carefully tailoring each step to the ore’s characteristics, the scheelite beneficiation process maximizes tungsten recovery while ensuring a high-grade concentrate.

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