What Are the Common Processes Used to Extract Gold Ores?
Extracting gold from ores involves several processes, which can vary depending on the type of ore and its composition. Here are the most common methods used to extract gold:
1. Gravity Separation
- Description: This method relies on the difference in density between gold and other minerals. Gold, being denser, is separated from lighter materials.
- Process:
- Crushed ore is passed through equipment like shaking tables, jigs, or sluice boxes.
- Gold settles at the bottom, while lighter materials are washed away.
- Common Use: Effective for free-milling gold and placer deposits.
2. Cyanidation (Cyanide Leaching)
- Description: This is the most widely used process for extracting gold from low-grade ores.
- Process:
- The crushed ore is mixed with a dilute cyanide solution, which dissolves the gold.
- Gold is then recovered from the solution using activated carbon or zinc precipitation.
- Variants:
- Heap Leaching: Ores are stacked in heaps, and cyanide solution is sprayed over them.
- Tank Leaching: Ore is finely ground and mixed in tanks with cyanide solution.
- Environmental Concern: Cyanide is toxic, so strict environmental controls are required.
3. Amalgamation
- Description: This is an older, less common process that uses mercury to extract gold.
- Process:
- Crushed ore is mixed with mercury, which binds with gold to form an amalgam.
- The amalgam is then heated to vaporize the mercury, leaving gold behind.
- Drawbacks:
- Mercury is highly toxic and harmful to the environment.
- Its use has been largely phased out due to health and environmental concerns.
4. Flotation
- Description: This method is used for ores where gold is associated with sulfide minerals.
- Process:
- Crushed ore is mixed with water, chemicals, and air in flotation cells.
- Gold and sulfides attach to air bubbles and float to the surface, where they are skimmed off.
- Common Use: Effective for refractory gold ores with sulfide minerals.
5. Roasting and Pressure Oxidation
- Description: These methods are used to process refractory gold ores, which contain minerals like pyrite or arsenopyrite that trap gold.
- Process:
- Roasting: The ore is heated in the presence of oxygen to oxidize sulfides and release gold.
- Pressure Oxidation: Ore is treated in an autoclave under high pressure and temperature to oxidize sulfides.
- Follow-Up: Gold is extracted using cyanidation after the refractory minerals are broken down.
6. Bioleaching (Biological Oxidation)
- Description: Microorganisms are used to break down sulfide minerals in refractory gold ores, making gold accessible.
- Process:
- Bacteria like Acidithiobacillus ferrooxidans are introduced to oxidize sulfides in the ore.
- Once the sulfides are broken down, cyanidation is used to recover gold.
- Advantages: Environmentally friendly compared to roasting.
7. Smelting
- Description: This is used to extract gold from concentrates or high-grade ore.
- Process:
- The ore is heated in a furnace along with fluxes like silica and borax.
- Impurities form a slag, while molten gold settles at the bottom and is poured off.
- Common Use: Often follows gravity or flotation processes.
8. Chlorination
- Description: Gold is dissolved using chlorine gas or a chlorinated solution.
- Process:
- Crushed ore is treated with chlorine gas or a mixture of hydrochloric acid and hypochlorite.
- Gold is then recovered from the solution.
- Drawbacks: Less common due to safety and environmental issues.
9. Thiosulfate Leaching
- Description: This is an alternative to cyanidation, using thiosulfate as the leaching agent.
- Process:
- Gold is dissolved in a thiosulfate solution and recovered using ion exchange or resins.
- Advantages: Non-toxic and more environmentally friendly than cyanide.
- Applications: Suitable for ores with high copper content or carbonaceous materials.
10. Gravity-Cyanidation Combination
- Description: Combines gravity separation with cyanidation for optimal recovery.
- Process:
- Gravity separation is used to recover coarse gold.
- Cyanidation is applied to recover fine gold from the leftover ore.
- Advantages: Maximizes gold recovery.
11. Electrolytic Gold Recovery
- Description: Used to recover gold from cyanide solutions or electronic scrap.
- Process:
- Gold ions in solution are reduced to metallic gold using an electrical current.
- Applications: Refining and recycling.
Factors Influencing Process Selection:
- Ore Type: Free-milling, refractory, or sulfide ores.
- Gold Particle Size: Coarse or fine gold.
- Economic Feasibility: Cost of processing and recovery.
- Environmental Regulations: Toxicity of chemicals used.
By combining these processes, miners can optimize gold recovery while minimizing environmental impact.
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